Can I add two different materials( different Reflectance for interior and exterior surface) on a single surface for daylight simulation

Hi Everyone @mostapha and @chris @devang , I am dealing with complex geometry for daylight simulation. This is an existing building and it has many exterior finishes in different colors. At the same time, it has a different interior reflectance. I am creating a single surface model for the daylighting simulation. Can I add two different materials for interior and exterior reflectance on the same surface? Or I need to create two different surfaces for exterior and interior for adding two different materials?

Did you check this and this?