So, a couple of things. If you are talking about the heat loss through the assembly, You should check out Ed May’s post in the link below. He goes through Psi values and everything else.
https://discourse.ladybug.tools/t/using-honeybee-therm-to-calculate-psi-values/3328/6
If you want the surface temperatures of each edge, you specified them in your boundaries. Inside are is typically set around 22C and outside should be based on your EPW file for that location.
I will look at your files later. Hope this helps